Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2000-03-09
J. Phys. Soc. Jpn. 69 (2000) 2751.
Physics
Condensed Matter
Strongly Correlated Electrons
4 pages, 5 eps figures, submitted to J. Phys. Soc. Jpn
Scientific paper
10.1143/JPSJ.69.2751
23Na NMR spectrum measurements in alpha'-NaV2O5 with a single- crystalline sample are reported. In the charge-ordered phase, the number of inequivalent Na sites observed is more than that expected from the low-temperature structures of space group Fmm2 reported so far. This disagreement indicates that the real structure including both atomic displacement and charge disproportionation is of lower symmetry. It is suggested that zigzag ordering is the most probable. The temperature variation of the NMR spectra near the transition temperature is incompatible with that of second-order transitions. It is thus concluded that the charge ordering transition is first-order.
Goto Atsushi
Isobe Masahiko
Ninomiya Emi
Ohama Tetsuo
Sawa Hiroshi
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