Weak and Strong-Coupling Electrostatic Interactions between Asymmetrically Charged Planar Surfaces

Details Weak and Strong-Coupling Electrostatic Interactions between Asymmetrically Charged Planar Surfaces Weak and Strong-Coupling Electrostatic Interactions between Asymmetrically Charged Planar Surfaces

2009-05-23

arxiv.org/abs/0905.3851v1

Phys. Rev. E 78, 061105 (2008)

Physics

Condensed Matter

Soft Condensed Matter

15 pages, 8 figures

Scientific paper

10.1103/PhysRevE.78.061105

We compare weak and strong coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte-Carlo simulations. Analytical results in both weak and strong coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak and the strong coupling limits.

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