Physics – Condensed Matter – Superconductivity
Scientific paper
2011-01-19
Physics
Condensed Matter
Superconductivity
8 pages, 7 figures, 1 table
Scientific paper
{\ss}-pyrochore KOs2O6, which shows superconductivity below ~ 9.7K, has been converted into KxOs2O6 (x < 2/3 - 1/2) electrochemically to show spin glass-like behavior below ~ 6.1K. Room temperature sample surface potential versus charge transfer scan indicates that there are at least two two-phase regions for x between 1 and 0.5. Rattling model of superconductivity for the title compound has been examined using electrochemical potassium de-intercalation. The significant reduction of superconducting volume fraction due to minor potassium reduction suggests the importance of defect and phase coherence in the rattling model. Magnetic susceptibility, resistivity, and specific heat measurement results have been compared between the superconducting and spin glass-like samples.
Chou Fang-Chieh
Lee Chaohong
Lee Lik Wee
Lin J. G.
Lin Jian-Yu
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