Polymeric alkali fullerides are stable in air

Details Polymeric alkali fullerides are stable in air Polymeric alkali fullerides are stable in air

1995-01-13

arxiv.org/abs/cond-mat/9501054v1

Appl. Phys. Lett. 66, 1015 (1995).

Physics

Condensed Matter

Scheduled for publication in Appl. Phys. Lett. 66, 20 Feb. 1995, typeset in REVTEX v3.0 in LaTeX. Postscript file including al

Scientific paper

10.1063/1.113590

Infrared transmission, electron spin resonance, and X-ray diffraction measurements show unambiguously that RbC$_{60}$ and KC$_{60}$ are stable in air, in contrast to Rb$_{6}$C$_{60}$ which decomposes rapidly upon exposure. The specimens studied transform into pure C$_{60}$ and other byproducts when heated above $100\dd $C, approximately the temperature of the orthorhombic-fcc phase transition. The stability of these compounds raises the possibility of applying them as protective layers for the superconducting fullerides.

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