Physics – Condensed Matter – Superconductivity
Scientific paper
2012-02-16
Physics
Condensed Matter
Superconductivity
5 pages, Submitted
Scientific paper
In this letter we show that the 2.80(8) {\mu}B/Fe block antiferromagnetic order of BaFe2Se3 transforms into stripe antiferromagnetic order in KFe2Se3 with a decrease in moment to 2.1(1) {\mu}B/Fe. This reduction is larger than expected from the change in electron count from Ba$^{2+}$ to K$^{+}$, and occurs with the loss of the displacements of Fe atoms from ideal positions in the ladders, as found by neutron pair distribution function analysis. Intermediate compositions remain insulating, and magnetic susceptibility measurements show a suppression of magnetic order. Together, these results imply an orbital-dependent selection of magnetic versus bonded behavior, driven by relative bandwidths and fillings.
Arpino K.
Caron J. M.
Llobet Anna
McQueen T. M.
Miller David C.
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