Physics – Condensed Matter – Materials Science
Scientific paper
2007-04-27
Physics
Condensed Matter
Materials Science
17 Pages, 5 Figures, Submitted to J. Chem. Phys
Scientific paper
10.1063/1.2969077
We present time-resolved photoluminescence measurements on two series of oligo-p-phenylenevinylene materials that self-assemble into supramolecular nanostructures with thermotropic reversibility in dodecane. One set of derivatives form chiral, helical stacks while the second set form less organised, frustrated stacks. Here we study the effects of supramolecular organisation on the resonance energy transfer rates. We measure these rates in nanoassemblies formed with mixed blends of oligomers and compare them with the rates predicted by Foerster theory. Our results and analysis show that control of supramolecular order in the nanometre lengthscale has a dominant effect on the efficiency and dimentionality of resonance energy transfer.
Daniel Clément
Herz Laura M.
Hoeben Freek J. M.
Jonkheijm Pascal
Makereel Francois
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