Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2007-10-17
Physics
Condensed Matter
Soft Condensed Matter
11 pages - 4 figures. To appear in JCP
Scientific paper
10.1063/1.2807228
The adsorption of charged colloids (macroions) onto an oppositely charged planar substrate is investigated theoretically. Taking properly into account the finite size of the macroions, unusual behaviors are reported. It is found that the role of the coions (the little salt-ions carrying the same sign of charge as that of the substrate) is crucial to understand the mechanisms involved in the process of macroion adsorption. In particular, the coions can accumulate near the substrate's surface and lead to a counter-intuitive {\it surface charge amplification}.
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