Intrinsic charge transport on the surface of organic semiconductors

Details Intrinsic charge transport on the surface of organic semiconductors Intrinsic charge transport on the surface of organic semiconductors

2004-03-23

arxiv.org/abs/cond-mat/0403575v1

Physics

Condensed Matter

Materials Science

10 pages, 4 figures

Scientific paper

10.1103/PhysRevLett.93.086602

The novel technique based on air-gap transistor stamps enabled realization of the intrinsic (not dominated by static disorder) transport of the electric-field-induced charge carriers on the surface of rubrene crystals over a wide temperature range. The signatures of the intrinsic transport are the anisotropy of the carrier mobility, mu, and the growth of mu with cooling. The anisotropy of mu vanishes in the activation regime at lower temperatures, where the charge transport becomes dominated by shallow traps. The deep traps, deliberately introduced into the crystal by X-ray radiation, increase the field-effect threshold without affecting the mobility. These traps filled above the field-effect threshold do not scatter the mobile polaronic carriers.

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