Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2000-01-12
Phys. Rev. B vol. 61, 11454 (2000)
Physics
Condensed Matter
Strongly Correlated Electrons
10 pages, 5 figures
Scientific paper
10.1103/PhysRevB.61.11454
The phonon dynamics of LiV2O5 single crystals is studied using infrared and Raman spectroscopy techniques. The infrared-active phonon frequencies and dielectric constants are obtained by oscillator fitting procedure of the reflectivity data measured at room temperature. The Raman scattering spectra are measured at room temperature and at T=10 K in all nonequivalent polarized configurations. The assignment of the phonons is done by comparing the infrared and Raman spectra of LiV2O5 and NaV2O5. The factor-group-analysis of the LiV2O5 crystal symmetry and of its constituent layers is performed to explain the symmetry properties of the observed modes. We concluded that layer symmetry dominates in the vibrational properties of this compound.
Gajic Radoš
Isobe Masaharu
Konstantinovic Milan J.
Moshchalkov Victor V.
Popovic Z. V.
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