Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2011-04-22
Phys. Rev. B 83 (2011) 233406
Physics
Condensed Matter
Statistical Mechanics
9 pages, 4 figures
Scientific paper
For a large class of lattice models we study the thermodynamic factor, $\Phi$, of the collective surface diffusion coefficient near a first-order phase transition between two phases at low temperatures. In a two-phase regime its dependence on the coverage, $\te$, is $\Phi \approx \te/[(\te-\te_-)(\te_+ - \te)N]$, where $N$ is the number of adsorption sites and $\te_\pm$ are the single-phase coverages at the transition. In the crossover between the two-phase and single-phase regimes $\Phi(\te)$ is shown to have a more complex behavior. The results are applied to a simple 2D lattice model.
Medved' Igor
Trnik Anton
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