Physics
Scientific paper
Jun 2010
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2010mss..confetg06f&link_type=abstract
"International Symposium On Molecular Spectroscopy, 65th Meeting, Held 21-25 June, 2010 at Ohio State University. http://molspec
Physics
Electronic (Uv/Vis/Nir)
Scientific paper
More than 1,000 CaF rovibronic levels, spanning the range n*=5, v=0 (42,500 cm-1) to n*=20, v=1 (47,500 cm-1), and sampling ℓ=0(s)-5(h) are fitted to a quantum defect model. This model consists of two currently separate pieces: the core-penetrating s, p, d, f series are fitted to the elements of an internuclear distance (R) and energy (E) dependent quantum defect matrix, μ(R,E); the core-nonpenetrating series are described by multipole (μ, Q, O) moments and polarizabilities (α, γ). The values of the fitted parameters agree well with ab initio computed values. Although the fitted parameters permit calculation of all spectra and all dynamics of CaF, the physical meanings of the parameters remain obscure.
Altunata S. N.
Coy Stephen L.
Field Robert W.
Jungen Ch.
Kay Jason
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