Relativistic effects in the electronic structure for the 3d paramagnetic ions

Details Relativistic effects in the electronic structure for the 3d paramagnetic ions Relativistic effects in the electronic structure for the 3d paramagnetic ions

1999-07-09

arxiv.org/abs/cond-mat/9907140v1

Physics

Condensed Matter

Strongly Correlated Electrons

9 pages in RevTex, 1 figure in EPS format This paper has been submitted to Phys.Rev.Lett

Scientific paper

It has been shown that relativistic spin-orbit effects have enormous influence on the electronic structure of the correlated electron systems 3dn. The s-o coupling produces the fine electronic structure with a large number of low- energy, < 10 meV, localized states, These states affect enormously electronic and magnetic properties of 3d-ion compounds at low- and room-temperature regions. It is inferred that the relativistic s-o effects and the multiplet structure on individual atoms are indispensable for the proper evaluation of the electronic structure of paramagnetic 3d ions.

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