Photoinduced Absorption Spectra of Halogen-Bridged Binuclear Metal Complexes: Possible Contrast between R_4_[Pt_2_(P_2_O_5_H_2_)_4_X]nH_2_O and Pt_2_(CH_3_CS_2_)_4_I

Details Photoinduced Absorption Spectra of Halogen-Bridged Binuclear Metal Complexes: Possible Contrast between R_4_[Pt_2_(P_2_O_5_H_2_)_4_X]nH_2_O and Pt_2_(CH_3_CS_2_)_4_I Photoinduced Absorption Spectra of Halogen-Bridged Binuclear Metal Complexes: Possible Contrast between R_4_[Pt_2_(P_2_O_5_H_2_)_4_X]nH_2_O and Pt_2_(CH_3_CS_2_)_4_I

2004-12-15

arxiv.org/abs/cond-mat/0412391v1

Physics

Condensed Matter

Strongly Correlated Electrons

J. Phys. Soc. Jpn. 74, No. 1 (2005)

Scientific paper

10.1143/JPSJ.74.250

The optical conductivity of photogenerated solitons in quasi-one-dimensional halogen-bridged binuclear metal (MMX) complexes is investigated with particular emphasis on a comparison between the two family compounds R_4_[Pt_2_(P_2_O_5_H_2_)_4_X]nH_2_O (X=Cl,Br,I;R=NH_4_,Na,K,...; pop=diphosphonate=P_2_O_5_H_2_^2-^) and Pt_2_(dta)_4_I (dta=dithioacetate=CH_3_CS_2_^-^). Soliton-induced absorption spectra for the pop complexes should split into two bands, while those for the dta complex should consist of a single band.

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Photoinduced Absorption Spectra of Halogen-Bridged Binuclear Metal Complexes: Possible Contrast between R_4_[Pt_2_(P_2_O_5_H_2_)_4_X]nH_2_O and Pt_2_(CH_3_CS_2_)_4_I does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

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