Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2009-10-17
Physics
Condensed Matter
Soft Condensed Matter
Scientific paper
A spontaneous buckling transition in thin layers of monodomain nematic liquid crystalline gel was observed by polarized light microscopy. The coupling between the orientational ordering of liquid crystalline solvent and the translational ordering of crosslinked polymer backbones inside the nematic gel contributes to such buckling transition. As the nematic mesogens become more ordered when the gel is cooled down from a higher gelation temperature, the polymeric backbones tend to elongate along the direction parallel to the nematic director, which is perpendicular to the rigid glass surfaces in the experimental setup. The shape change of such confined gel sample lead to the spontaneous buckling of polymeric network and the spatial modulation of nematic liquid crystalline director, which is observed as the stripe patterns. The instability analysis was used to explain such transitions, and the relationship between the critical field, stripe's wavelength and temperature can be explained qualitatively by the rubber elasticity theory for liquid crystalline gels.
Meng Guangnan
Meyer Robert B.
No associations
LandOfFree
Buckling transition of nematic gels in confined geometry does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Buckling transition of nematic gels in confined geometry, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Buckling transition of nematic gels in confined geometry will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-89520