Onsager model for a variable dielectric permittivity near an interface

Details Onsager model for a variable dielectric permittivity near an interface Onsager model for a variable dielectric permittivity near an interface

2003-04-03

arxiv.org/abs/cond-mat/0304087v1

Molecular Physics 101, 2559-2568 (2003)

Physics

Condensed Matter

Soft Condensed Matter

20 pages, 4 figures, submitted to Molecular Physics

Scientific paper

10.1080/0026897032000112892

Using a generalisation of an Onsager type approach, we are able to predict a dielectric permittivity profile of an inhomogeneous dipolar fluid in the presence of a dielectric interface. The reaction and cavity fields are calculated semi-analytically using bispherical coordinates. An asymptotic expression for the local permittivity is derived as a function of distance from the interface.

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