Generalized thermodynamics and kinetic equations: Boltzmann, Landau, Kramers and Smoluchowski

Physics – Condensed Matter – Statistical Mechanics

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Scientific paper

We propose a formal extension of thermodynamics and kinetic theories to a larger class of entropy functionals. Kinetic equations associated to Boltzmann, Fermi, Bose and Tsallis entropies are recovered as a special case. This formalism first provides a unifying description of classical and quantum kinetic theories. On the other hand, a generalized thermodynamical framework is justified to describe complex systems exhibiting anomalous diffusion. Finally, a notion of generalized thermodynamics emerges in the context of the the violent relaxation of collisionless stellar systems and two-dimensional vortices due to the existence of Casimir invariants and incomplete relaxation. A thermodynamical analogy can also be developed to analyze the nonlinear dynamical stability of stationary solutions of the Vlasov and 2D Euler-Poisson systems. On general grounds, we suggest that generalized entropies arise due to the existence of ``hidden constraints'' that modify the form of entropy that we would naively expect. Generalized kinetic equations are therefore ``effective'' equations that are introduced heuristically to describe complex systems.

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