Enthalpy recovery in semicrystalline polymers

Details Enthalpy recovery in semicrystalline polymers Enthalpy recovery in semicrystalline polymers

2000-04-04

arxiv.org/abs/cond-mat/0004029v1

Physics

Condensed Matter

Soft Condensed Matter

13 pages, 5 figures, LATEX

Scientific paper

Constitutive equations are derived for enthalpy recovery in polymeric glasses
after thermal jumps. The model is based on the theory of cooperative relaxation
in a version of the trapping concept. It is demonstrated that some critical
temperature and some critical degree of crystallinity exist above which the
energy landscape becomes homogeneous and structural relaxation ceases.

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