The Jahn-Teller theorem for 3d ions and their compounds

Details The Jahn-Teller theorem for 3d ions and their compounds The Jahn-Teller theorem for 3d ions and their compounds

2006-04-07

arxiv.org/abs/cond-mat/0604207v1

Physics

Condensed Matter

Strongly Correlated Electrons

2 pages, 2 figures embedded

Scientific paper

In contrary to customarily consideration of the Jahn-Teller theorem for 3d-ion compounds in the orbital space only we point out that it has to be considered in the spin-orbital space. It is despite the weakness of the intraatomic spin-orbit coupling. A direct motivation for this paper is an erroneous claim of a recent Phys. Rev. Lett. 96 (2006) 027201 paper that the high-spin t2g4eg2 state of the 3d6 configuration is not Jahn-Teller active.

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