Lennard-Jones binary mixture: a thermodynamical approach to glass transition

Details Lennard-Jones binary mixture: a thermodynamical approach to glass transition Lennard-Jones binary mixture: a thermodynamical approach to glass transition

1999-04-09

arxiv.org/abs/cond-mat/9904124v3

J. Chem. Phys. n.112, 2933 (2000)

Physics

Condensed Matter

Disordered Systems and Neural Networks

24 pages, 11 postscript figures. Revised version accepted for pubblication on J. Chem. Phys. Numerical precision of the comput

Scientific paper

10.1063/1.480866

We study the liquid-glass transition of the Lennard-Jones binary mixture introduced by Kob and Andersen from a thermodynamic point of view. By means of the replica approach, translating the problem in the study of a molecular liquid, we study the phase transition due to the entropy crisis and we find that the Kauzmann's temperature $\tk$ is $\sim 0.32$. At the end we compare analytical predictions with numerical results.

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