Quantum escape kinetics over a fluctuating barrier

Details Quantum escape kinetics over a fluctuating barrier Quantum escape kinetics over a fluctuating barrier

2006-02-23

arxiv.org/abs/cond-mat/0602553v1

J. Chem. Phys. Vol-123, Page-224104, (2005)

Physics

Condensed Matter

Statistical Mechanics

Scientific paper

The escape rate of a particle over a fluctuating barrier in a double well potential exhibits resonance at an optimum value of correlation time of fluctuation. This has been shown to be important in several variants of kinetic model of chemical reactions . We extend the analysis of this phenomenon of resonant activation to quantum domain to show how quantization significantly enhances resonant activation at low temperature due to tunneling.

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