Polymer Chain Orientations in KC60 and RbC60 : Structural Analysis and Relation with Electronic Properties

Details Polymer Chain Orientations in KC60 and RbC60 : Structural Analysis and Relation with Electronic Properties Polymer Chain Orientations in KC60 and RbC60 : Structural Analysis and Relation with Electronic Properties

1998-09-24

arxiv.org/abs/cond-mat/9809327v1

Physics

Condensed Matter

Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals, to appear in Synthetic Metals

Scientific paper

First single crystal X-ray diffraction studies of polymerized KC60 and RbC60 are presented. While powder diffraction studies showed no definite structural differences, the single crystal diffraction data analysis reveals different relative chain orientations in the two compounds. They are discussed in relation with semi-empirical energy calculations. The structural difference between KC60 and RbC60 may be a key feature for the understanding of their contrasted conducting and magnetic properties.

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