Physics – Condensed Matter – Statistical Mechanics
Scientific paper
1998-09-24
Physics
Condensed Matter
Statistical Mechanics
7 pages, 5 figures, submitted to J. Phys. A
Scientific paper
10.1088/0305-4470/32/16/008
We investigate, both analytically and by computer simulation, the kinetics of a microscopic model of hard rods adsorbing on a linear substrate. For a small, but finite desorption rate, the system reaches the equilibrium state very slowly, and the long-time kinetics display three successive regimes: an algebraic one where the density varies as $1/t$, a logarithmic one where the density varies as $1/ln(t)$, followed by a terminal exponential approach. A mean-field approach fails to predict the relaxation rate associated with the latter. We show that the correct answer can only be provided by using a systematic description based on a gap-distribution approach.
Talbot John
Tarjus Gilles
Viot Pascal
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