Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2008-06-27
J. Phys.: Condens. Matter, 20, 322201 (2008)
Physics
Condensed Matter
Strongly Correlated Electrons
Published version, minor changes
Scientific paper
10.1088/0953-8984/20/32/322201
We report the synthesis and basic physical properties of single crystals of CaFe2As2, an isostructural compound to BaFe2As2 which has been recently doped to produce superconductivity. CaFe2As2 crystalizes in the ThCr2Si2 structure with lattice parameters a = 3.907(4) A and c = 11.69(2) A. Magnetic susceptibility, resistivity, and heat capacity all show a first order phase transition at T_0 171 K. The magnetic susceptibility is nearly isotropic from 2 K to 350 K. The heat capacity data gives a Sommerfeld coefficient of 8.2 +- 0.3 mJ/molK2, and does not reveal any evidence for the presence of high frequency (> 300 K) optical phonon modes. The Hall coefficient is negative below the transition indicating dominant n-type carriers.
Bauer Eric D.
Klimczuk T.
Ronning Filip
Thompson Daniel J.
Volz H.
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