Physics – Condensed Matter – Materials Science
Scientific paper
2005-05-13
Physics
Condensed Matter
Materials Science
10 pages, 4 figures
Scientific paper
10.1557/jmr.2006.0170
We report here investigations on the instability in luminescence of bare (TOPO-stabilized) and CdS- capped CdSe particles under infrared radiation. During photo-thermal annealing the formation of oxide layers on the surfaces of the particles create defect states. Consequently there is a reduction in particle size. These two effects control the light output from the samples. We make a quantitative comparison of the stability of bare CdSe and core-shell type CdSe-CdS particles under photo-annealing. Using diffusion theory, we show that the volume of the oxide layer, adhered to the crystallites, play a dominant role in controlling the luminosity of the particles.
Roy Anirban
Singha Achintya
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