Physics – Condensed Matter – Materials Science
Scientific paper
2001-03-16
Physics
Condensed Matter
Materials Science
Scientific paper
10.1063/1.1376145
We have studied thermodynamics of the Mg-B system with the modeling technique CALPHAD using a computerized optimization procedure. Temperature-composition, pressure-composition, and pressure-temperature phase diagrams under different conditions are obtained. The results provide helpful insights into appropriate processing conditions for thin films of the superconducting phase, MgB2, including the identification of the pressure/temperature region for adsorption-controlled growth. Due to the high volatility of Mg, MgB2 is thermodynamically stable only under fairly high Mg overpressures for likely growth temperatures. This constraint places severe temperature constraints on deposition techniques employing high vacuum conditions.
Li Qian
Liu Zi-Kui
Schlom Darrell G.
Xi Xiangdong
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