Mixed-Valence Tetranuclear Manganese Single-Molecule Magnets

Details Mixed-Valence Tetranuclear Manganese Single-Molecule Magnets Mixed-Valence Tetranuclear Manganese Single-Molecule Magnets

2001-09-26

arxiv.org/abs/cond-mat/0109496v1

Physics

Condensed Matter

33 pages, 5 tables, 23 figures

Scientific paper

The preparations, X-ray structures, and detailed physical characterizations
are presented for two new mixed-valence tetranuclear manganese complexes that
function as single-molecule magnets (SMM's): [Mn4(hmp)6Br2(H2O)2]Br2.4H2O and
[Mn4(6-me-hmp)6Cl4].4H2O, where hmp- is the anion of 2-hydroxymethylpyridine
and 6-me-hmp- is the anion of 6-methyl-2-hydroxymethylpyridine.

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