Physics – Condensed Matter – Materials Science
Scientific paper
2006-06-02
Physics
Condensed Matter
Materials Science
Scientific paper
10.1021/ma062607r
By applying local primitive path and Rouse modes analysis we study the chains conformations, local dynamics and viscosity of a model polymer melt in a polymer-wall interface. We establish that the presence of a repulsive wall leads to acceleration of the dynamics both for unentangled and weakly entangled melts and to a depletion in the entanglement density in the wall vicinity. When the surface bears some grafted chains, we show that the melt chains are accelerated in the unentangled regime and slowed down in the entangled regime. By analyzing the primitive paths we attribute the observed slowdown to an increase in the entanglement density in the interfacial layer. The presence of a relatively small density of grafting sites thus leads to improved mechanical properties (reinforcement) and decreases locally the entanglement length even if the surface is repulsive.
Barrat Jean Louis
Vladkov Mihail
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