Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
1997-07-11
Physics
Condensed Matter
Soft Condensed Matter
17 double column pages prepared by RevTex, 15 eps figures included in text, 2 gif figures for Fig. 14
Scientific paper
10.1103/PhysRevE.57.610
Inverse nematic emulsions in which surfactant-coated water droplets are dispersed in a nematic host fluid have distinctive properties that set them apart from dispersions of two isotropic fluids or of nematic droplets in an isotropic fluid. We present a comprehensive theoretical study of the distortions produced in the nematic host by the dispersed droplets and of solvent mediated dipolar interactions between droplets that lead to their experimentally observed chaining. A single droplet in a nematic host acts like a macroscopic hedgehog defect. Global boundary conditions force the nucleation of compensating topological defects in the nematic host. Using variational techniques, we show that in the lowest energy configuration, a single water droplet draws a single hedgehog out of the nematic host to form a tightly bound dipole. Configurations in which the water droplet is encircled by a disclination ring have higher energy. The droplet-dipole induces distortions in the nematic host that lead to an effective dipole-dipole interaction between droplets and hence to chaining.
Currier Nathan
Lubensky Tom. C.
Pettey David
Stark Holger
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