Site Occupancy and Lattice Parameters in Sigma-Phase Co-Cr alloys

Details Site Occupancy and Lattice Parameters in Sigma-Phase Co-Cr alloys Site Occupancy and Lattice Parameters in Sigma-Phase Co-Cr alloys

2010-10-12

arxiv.org/abs/1010.2373v1

Acta Cryst. Section B, 68 (2012) 123

Physics

Condensed Matter

Materials Science

5 figures

Scientific paper

10.1107/S0108768112006234

Neutron diffraction technique was used to study distribution of Co and Cr atoms over different lattice sites as well as lattice paramaters in sigma-phase Co100-xCrx compounds with x = 57.0, 62.7 and 65.8. From the diffractograms recorded in the temperature range of 4.2 - 300 K it was found that all five sites A, B, C, D and E are populated by both kinds of atoms. Sites A and D are predominantly occupied by Co atoms while sites B, C and E by Cr atoms. The unit cell parameters a and c, hence the unit cell volume, increase with x, the increase being characteristic of the lattice paramater and temperature. Both a and c show a non-linear increase with temperature.

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