A Raman Study of Morphotropic Phase Boundary in PbZr1-xTixO3 at low temperatures

Physics – Condensed Matter – Materials Science

Scientific paper

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5 pages, 4 figures

Scientific paper

10.1103/PhysRevB.63.184105

Raman spectra of PbZr1-xTixO3 ceramics with titanium concentration varying between 0.40 and 0.60 were measured at 7 K. By observing the concentration-frequency dependence of vibrational modes, we identified the boundaries among rhombohedral, monoclinic, and tetragonal ferroelectric phases. The analysis of the spectra was made in the view of theory group analysis making possible the assignment of some modes for the monoclinic phase.

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