Attraction Between Like-Charge Surfaces in Polar Mixtures

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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6 pages, 6 figures

Scientific paper

We examine the force between two charged surfaces immersed in aqueous mixtures having a coexistence curve. For a homogeneous water-poor phase, as the distance between the surfaces is decreased, a water-rich phase condenses at a distance $D_t$ in the range 1-100nm. At this distance the osmotic pressure can become negative leading to a long-range attraction between the surfaces. The osmotic pressure vanishes at a distance $D_e

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