On the origin of biquadratic exchange in spin 1 chains

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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4 pages, 4 Postscript figures. To appear in Eur. Phys. J B as a Rapid Note

Scientific paper

10.1007/s100510070242

One dimensional spin 1 systems may have a rich phase diagram including Haldane gap and dimerized phases if the usually very small biquadratic exchange becomes significant. We show that this unlikely condition may be fulfilled in electron systems with quasi-degenerate orbitals. This mechanism may have been experimentally realized in the spin 1 chain LiVGe$_2$O$_6$. The implications for the exploration of the physics and quantum chemistry of spin 1 chains are discussed.

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