Vibrational properties of sp carbon atomic wires in cluster-assembled carbon films

Details Vibrational properties of sp carbon atomic wires in cluster-assembled carbon films Vibrational properties of sp carbon atomic wires in cluster-assembled carbon films

2010-03-04

arxiv.org/abs/1003.1016v3

Phys. Status Solidi B 247, 2017 (2010)

Physics

Condensed Matter

Mesoscale and Nanoscale Physics

in print in Physica Status Solidi

Scientific paper

Linear chains made by a single row of sp-hybridized carbon are predicted to display fascinating mechano-electronic properties connected with their termination and stabilization inside realistic carbon structures. The present work describes how the computed vibrational properties of cumulenic and polyynic carbon chains allow one to interpret the carbynic features observed in Raman spectra of cluster-assembled sp-sp2 films. The overall picture is consistent with the measured decay of the sp components induced by air or oxygen exposure.

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