On the completeness of describing an equilibrium canonical ensemble using a pair distribution function

Details On the completeness of describing an equilibrium canonical ensemble using a pair distribution function On the completeness of describing an equilibrium canonical ensemble using a pair distribution function

2004-05-12

arxiv.org/abs/cond-mat/0405256v1

Physics

Condensed Matter

Statistical Mechanics

10 pages, no figures

Scientific paper

It is shown that in equilibrium a canonical ensemble of particles with two-particle interaction the Gibbs distribution function may be expressed uniquely through a pair distribution function. It means, that for given values of the particle number $N$, volume $V$, and temperature $T$, the pair distribution function contains as many information about the system as a full Gibbs distribution. The latter is represented as a series expansion in the pair distribution function. A recurrence relation system is constructed, which allows all terms of this expansion to be calculated successively.

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