Density anomaly in a competing interactions lattice gas model

Details Density anomaly in a competing interactions lattice gas model Density anomaly in a competing interactions lattice gas model

2004-09-06

arxiv.org/abs/cond-mat/0409138v1

J. Phys.: Cond. Mat. 17, 399 (2005)

Physics

Condensed Matter

Statistical Mechanics

Scientific paper

10.1088/0953-8984/17/3/001

We study a very simple model of a short-range attraction and an outer shell repulsion as a test system for demixing phase transition and density anomaly. The phase-diagram is obtained by applying mean field analysis and Monte Carlo simulations to a two dimensional lattice gas with nearest-neighbors attraction and next-nearest-neighbors repulsion (the outer shell). Two liquid phases and density anomaly are found. The coexistence line between these two liquid phases meets a critical line between the fluid and the low density liquid at a tricritical point. The line of maximum density emerges in the vicinity of the tricritical point, close to the demixing transition.

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