A variational approach to necklaces formation in polyelectrolytes

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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6 pages, 4 figures (unfortunately big). Requires revtex, epsf

Scientific paper

10.1021/ma971767n

By means of a variational approach we study the conditions under which a
polyelectrolyte in a bad solvent will undergo a transition from a rod-like
structure to a ``necklace'' structure in which the chain collapses into a
series of globules joined by stretched chain segments.

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