Synthesis of RuSr2(Ln3/4Ce1/4)2Cu2O10 magneto-superconducting compounds with Ln = Ho, Y and Dy by high-pressure high-temperature (HPHT) technique

Physics – Condensed Matter – Superconductivity

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12 pages with TEXT and 5 Figs., Submitted to Physica C

Scientific paper

10.1016/S0921-4534(02)02814-9

The samples of composition RuSr2(Ln3/4Ce1/4)2Cu2O10 with Ln = Ho, Y and Dy. being synthesized by high pressure high temperature (6Gpa, 1200 0C) solid state synthesis route do crystallize in space group I4/mmm. These samples exhibit magnetic transitions at ~150 K with significant branching of zfc (zero-field-cooled) and fc (field-cooled) magnetization and a sharp cusp in zfc at ~ 100 K, followed by a superconducting transition at lower temperatures. All the compounds show typical ferromagnetic hysteresis loops in magnetic moment (M) versus field (H) magnetization at 5 K. Near saturation of the moments at 5 K is achieved in above 5 T (Tesla) applied fields with a value of ~ 0.80 muB. At low temperatures (5 K) these compounds exhibit both superconductivity and ferromagnetism. To our knowledge these are first successfully synthesized Ru-1222 compounds with various lanthanides including Y, Dy, and Ho. The results are compared with widely reported Gd/Ru-1222 compound.

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