Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2009-06-04
Phys. Rev. E 80, 011707 (2009)
Physics
Condensed Matter
Soft Condensed Matter
7 pages, including 12 postscript figures, uses REVTeX 4
Scientific paper
10.1103/PhysRevE.80.011707
Recent experiments and simulations have shown that two-dimensional systems can form tetratic phases with four-fold rotational symmetry, even if they are composed of particles with only two-fold symmetry. To understand this effect, we propose a model for the statistical mechanics of particles with almost four-fold symmetry, which is weakly broken down to two-fold. We introduce a coefficient $\kappa$ to characterize the symmetry breaking, and find that the tetratic phase can still exist even up to a substantial value of $\kappa$. Through a Landau expansion of the free energy, we calculate the mean-field phase diagram, which is similar to the result of a previous hard-particle excluded-volume model. To verify our mean-field calculation, we develop a Monte Carlo simulation of spins on a triangular lattice. The results of the simulation agree very well with the Landau theory.
Geng Jun
Selinger Jonathan V.
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