Theory of Spontaneous Polarization of Endohedral Fullerenes

Details Theory of Spontaneous Polarization of Endohedral Fullerenes Theory of Spontaneous Polarization of Endohedral Fullerenes

1997-09-16

arxiv.org/abs/cond-mat/9709186v2

Phys. Rev. Lett. 80 (1998) 3735

Physics

Condensed Matter

4 pages, REVTEX, 1 Postscript figure. [Phys. Rev. Lett. (in press)]

Scientific paper

10.1103/PhysRevLett.80.3735

A pseudo-Jahn-Teller model describing central atom distortions is proposed
for endohedral fullerenes of the form A@C$_{60}$ where A is either a rare gas
or a metal atom. A critical (dimensionless) coupling $g_c$ is found, below
which the symmetric configuration is stable and above which inversion symmetry
is broken. Vibronic parameters are given for selected endohedral fullerenes.

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