Positional disorder of Ba in the thermoelectric germanium clathrate Ba6Ge25

Details Positional disorder of Ba in the thermoelectric germanium clathrate Ba6Ge25 Positional disorder of Ba in the thermoelectric germanium clathrate Ba6Ge25

2003-04-11

arxiv.org/abs/cond-mat/0304291v1

Physics

Condensed Matter

Materials Science

5 pages and 4 figures, submitted to Solid State Communications

Scientific paper

10.1016/S0038-1098(03)00372-7

The local structure of Ba6Ge25 has been studied by x-ray diffraction and the
atomic pair distribution function technique at 40 K and room temperature.
Unambiguous evidence has been found that two out of three types of Ba atoms in
Ba6Ge25 move off their positions and become locked in split sites at low
temperatures.

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