Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
1999-02-02
Physics
Condensed Matter
Soft Condensed Matter
4 pages, 2 figures, accepted Phys. Rev. Lett
Scientific paper
The effect of polydispersity on the freezing transition of hard spheres is examined within a moment description. At low polydispersities a single fluid-to-crystal transition is recovered. With increasing polydispersity we find a density above which the crystal melts back into an amorphous phase. The range of densities over which the crystalline phase is stable shrinks with increasing polydispersity until, at a certain level of polydispersity, the crystal disappears completely from the equilibrium phase diagram. The two transitions converge to a single point which we identify as the polydisperse analogue of a point of equal concentration. At this point, the freezing transition is continuous in a thermodynamic sense.
Bartlett Paul
Warren Patrick B.
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