From Finite to Infinite Range Order via Annealing: The Causal Architecture of Deformation Faulting in Annealed Close-Packed Crystals

Physics – Condensed Matter – Materials Science

Scientific paper

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7 pages, 6 figures; See http://www.santafe.edu/projects/CompMech/papers/iro.html

Scientific paper

10.1016/j.physleta.2004.02.077

We analyze solid-state phase transformations that occur in zinc-sulfide crystals during annealing using a random deformation-faulting mechanism with a very simple interaction between adjacent close-packed double layers. We show that, through annealing, infinite-range structures emerge from initially short-range crystal order. That is, widely separated layers carry structurally significant information and so layer stacking cannot be completely described by any finite-range Markov process. We compare our results to two experimental diffraction spectra, finding excellent agreement.

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