Comment on "Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes"

Details Comment on "Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes" Comment on "Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes"

2003-10-20

arxiv.org/abs/cond-mat/0310456v1

Physics

Condensed Matter

Strongly Correlated Electrons

Revtex, 2 pages, 1 eps figure

Scientific paper

The low-lying singlet and triplet spectrum in conjugated polymers clearly
show that the mechanism proposed by Lin et al. to explain their electric field
dependence of singlet to triplet yield ratios is wrong. This comment, from
theoretical spectrum obtained for long polyenes, shows that the phonon
bottleneck proposed by Lin et al. for triplets in polyenes cannot exist.

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