Physics – Condensed Matter – Materials Science
Scientific paper
2004-11-24
Phys. Rev. Lett. 94, 027402 (2005)
Physics
Condensed Matter
Materials Science
5 pages, 3 figures
Scientific paper
10.1103/PhysRevLett.94.027402
We find that the optical properties of carbon nanotubes reflect remarkably strong effects of exciton-phonon coupling. Tight-binding calculations show that a significant fraction of the spectral weight of the absorption peak is transferred to a distinct exciton+phonon sideband, which is peaked at around 200 meV above the main absorption peak. This sideband provides a distinctive signature of the excitonic character of the optical transition. The exciton-phonon coupling is reflected in a dynamical structural distortion, which contributes a binding energy of up to 100 meV. The distortion is surprisingly long-ranged, and is strongly dependent on chirality.
Avouris Phaedon
Perebeinos Vasili
Tersoff Jerry
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