Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2005-07-15
J. Stat. Phys. 125, 455-471, 2006
Physics
Condensed Matter
Statistical Mechanics
9 pages, revtex4, 3 figures. Changes in v2: sections added on applications plus many new references; contains an addendum not
Scientific paper
10.1007/s10955-006-9174-z
We discuss a subtlety involved in the calculation of multifractal spectra when these are expressed as Legendre-Fenchel transforms of functions analogous to free energy functions. We show that the Legendre-Fenchel transform of a free energy function yields the correct multifractal spectrum only when the latter is wholly concave. If the spectrum has no definite concavity, then the transform yields the concave envelope of the spectrum rather than the spectrum itself. Some mathematical and physical examples are given to illustrate this result, which lies at the root of the nonequivalence of the microcanonical and canonical ensembles. On a more positive note, we also show that the impossibility of expressing nonconcave multifractal spectra through Legendre-Fenchel transforms of free energies can be circumvented with the help of a generalized free energy function, which relates to a recently introduced generalized canonical ensemble. Analogies with the calculation of rate functions in large deviation theory are finally discussed.
Beck Christian
Touchette Hugo
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