Physics – Condensed Matter – Materials Science
Scientific paper
2011-08-23
Phys. Rev. B 84, 085414 (2011)
Physics
Condensed Matter
Materials Science
7 pages, 4 figures, 3 tables
Scientific paper
10.1103/PhysRevB.84.085414
Glycine molecules deposited on Cu(100) surface give rise to an anisotropic free-electron-like (FEL) electronic dispersion in its p(2$\times$4) superstructure, as reported in recent experiments [Phys. Rev. Lett. {\bf 99}, 216102 (2007); J. Am. Chem. Soc. {\bf 129}, 740 (2007)]. Using density functional theory and exhaustively calculating sixteen possible structures, we have determined the molecular arrangement that can give the experimentally observed FEL behavior. Eight configurations, among the sixteen, were not investigated before in the literature and one of them (denoted Str-3) is able to provide the FEL behavior in excellent agreement with the experiments. In addition, the particular configuration Str-3 satisfies other criteria of the observed p(2$\times$4) superstructure, e.g. chirality and cleavable orientation.
Guo Hong
Hu Zhi-Xin
Ji Wei
No associations
LandOfFree
Molecular ordering of glycine on Cu(100): the p($2\times4$) superstructure does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Molecular ordering of glycine on Cu(100): the p($2\times4$) superstructure, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Molecular ordering of glycine on Cu(100): the p($2\times4$) superstructure will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-376989