Many-particle effects in adsorbed magnetic atoms with easy-axis anisotropy: the case of Fe on CuN/Cu(100) surface

Physics – Condensed Matter – Mesoscale and Nanoscale Physics

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18 pages, 7 figures

Scientific paper

10.1088/1367-2630/12/6/063040

We study the effects of the exchange interaction between an adsorbed magnetic atom with easy-axis magnetic anisotropy and the conduction-band electrons from the substrate. We model the system using an anisotropic Kondo model and we compute the impurity spectral function which is related to the differential conductance (dI/dV) spectra measured using a scanning tunneling microscope. To make contact with the known experimental results for iron atoms on the CuN/Cu(100) surface [Hirjibehedin et al., Science {\bf 317}, 1199 (2007)], we calculated the spectral functions in the presence of an external magnetic field of varying strength applied along all three spatial directions. It is possible to establish an upper bound on the coupling constant J: in the range of the magnetic fields for which the experimental results are currently known (up to 7T), the low-energy features in the calculated spectra agree well with the measured dI/dV spectra if the exchange coupling constant J is at most half as large as that for cobalt atoms on the same surface. We show that for even higher magnetic field (between 8 and 9T) applied along the ``hollow direction'', the impurity energy states cross, giving rise to a Kondo effect which takes the form of a zero-bias resonance. The paper introduces an approach for calculating the expectation values of global spin operators and all components of the impurity magnetic susceptibility tensor in numerical renormalization group (NRG) calculations with no spin symmetry. An appendix contains a density-functional-theory (DFT) study of the Cu and Fe adsorbates on CuN/Cu(100) surface: we compare magnetic moments, as well as orbital energies, occupancies, centers, and spreads by calculating the maximally localized Wannier orbitals of the adsorbates.

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