Fluctuation-driven heterogeneous chemical processes

Details Fluctuation-driven heterogeneous chemical processes Fluctuation-driven heterogeneous chemical processes

2007-10-29

arxiv.org/abs/0710.5540v1

Physics

Condensed Matter

Other Condensed Matter

23 pages, 19 figures

Scientific paper

We explore a new framework for describing the kinetics of a heterogeneous chemical reaction where two particles of the same chemical species form a reaction product of another chemical species on the surface of a seed particle. Traditional treatments neglect the effect of statistical fluctuations in populations. We employ techniques in a manner analogous to the treatment of quantum systems to develop a stochastic description of processes beyond the mean field approximation.

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