Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2010-04-21
Physics
Condensed Matter
Soft Condensed Matter
7 pages, 4 figures
Scientific paper
We applied the mean-field approach to a columnar bundle assembled by the parallel arrangement of stiff polyelectrolyte rods in a salt bath. The electrostatic potential can be divided into two regions: inside the bundle for condensed counter-ions, and outside the bundle for free small ions. To determine the distribution of condensed counter-ions inside the bundle, we use a local self-consistent condition that depends on the charge density, the electrostatic potential, and the net polarization. The results showed that, upon bundle formation, the electric charge of polyelectrolytes, even those inside the bundle, tend to survive in an inhomogeneous manner, and thus their width remains finite under thermal equilibrium because of the long-range effect of charge instability.
Saito Takuya
Yoshikawa Kenichi
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