From valence bond solid to unconventional superconductivity in the organic charge-transfer solids

Details From valence bond solid to unconventional superconductivity in the organic charge-transfer solids From valence bond solid to unconventional superconductivity in the organic charge-transfer solids

2008-07-28

arxiv.org/abs/0807.4523v1

Synthetic Metals 159 21-22 (2009)

Physics

Condensed Matter

Superconductivity

4 pages, 4 figures, submitted to Synthetic Metals

Scientific paper

10.1016/j.synthmet.2009.08.018

We show that superconductivity is absent within the 1/2-filled band triangular lattice repulsive Hubbard model that has been proposed for organic charge-transfer solids. We posit that organic superconductivity is rather reached from a Bond-Charge Density Wave that either constitutes the insulating state proximate to superconductivity, or is extremely close in energy to the antiferromagnetic state, and replaces the latter under pressure. The Bond-Charge Density Wave can be described within an effective attractive $U$ extended Hubbard Hamiltonian with repulsive nearest neighbor interaction $V$. A first-order transition from the insulating to the superconducting state occurs within the model with increasing frustration.

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